Air-broadening in near-infrared carbon dioxide line shapes: Quantifying contributions from O2, N2, and Ar
نویسندگان
چکیده
We measured air broadening in the (30012) ← (00001) carbon dioxide (CO2) band up to Jʺ = 50 using frequency-agile rapid scanning cavity ring-down spectroscopy. By synthetic samples with varying levels of nitrogen, oxygen, and argon, multi-spectrum fitting allowed for collisional terms each major component be simultaneously determined addition advanced line shape parameters at atmospherically relevant CO2 mixing ratios. These values were compared broadener-specific from literature. Fits spectra also constrained results requantized classical molecular dynamic simulations. show that this approach enables differentiation between narrowing mechanisms retrieved experimental limited signal-to-noise ratio.
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ژورنال
عنوان ژورنال: Journal of Quantitative Spectroscopy & Radiative Transfer
سال: 2021
ISSN: ['1879-1352', '0022-4073']
DOI: https://doi.org/10.1016/j.jqsrt.2021.107669